Population Inversions in an Expanding Gas

It is well established that population inversions between the (001) and (100) vibrational energy levels of CO2 can be created by rapid expansions of CO2-N2-H2O or He mixtures through supersonic nozzles. New experimental results are presented for such inversions. These experiments were conducted in both the 3-Megawatt Arc Tunnel and the 12.7 cm Shock Tunnel at the Naval Ordnance Laboratory. The results support previously published theoretical predictions obtained with a numerical, time-dependent, nonequilibrium nozzle flow analysis employing a simplified vibrational kinetic model. This theory is also compared with experimental data obtained by other investigators. (Author).